I was trying to use a keyboard shortcut I set up for Windows Key + ` and accidentally fat-fingered the 1 instead. To my bewilderment Visual Studio launched. I hit it again and got another instance of VS. Windows+2 launched VMware and Windows+3 launched SQL Management Studio. After bumbling around for a bit, I realized that it was launching things in the order they were in my Quick Launch toolbar. Trying to get a friend excited about it revealed that it’s a new feature in Vista, whoops!